Katherine Walker High-resolution electrospray ionization mass spectrometry (ESI-MS) is an powerful technique for identifying organometallic intermediates in catalytic reactions.1-3 While identifying intermediates is not sufficient for fully understanding a mechanism, it provides one important piece of information that can be […]
Many enzymatic reactions catalyze reactants to products while populating short-lived intermediates. The development of time-resolved mass spectrometry offers high sensitivity and selectivity for studying the dynamic processes associated with the progress of the reaction in time. However, the rapid mixing […]